Experimental comparison of the Butler-Volmer and Marcus-Hush-Chidsey formalisms of electrode kinetics: The reduction of cyclooctatetraene at mercury hemispherical electrodes via cyclic and square wave voltammetries

Critical analysis of the Butler-Volmer and Marcus-Hush-Chidsey kinetic models is carried out through the study of the first one-electron reduction of cyclooctatetraene in DMSO at mercury hemispherical microelectrodes. This is an atypically slow process due to the conformational distortion taking pla...

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Bibliografische gegevens
Hoofdauteurs: Suwatchara, D, Rees, N, Henstridge, M, Laborda, E, Compton, R
Formaat: Journal article
Taal:English
Gepubliceerd in: 2012