Synthesis of titanium borylimido compounds supported by diamide-amine ligands and their reactions with alkynes
We report a combined synthetic, mechanistic, and computational (DFT) study of the synthesis of new diamide-amine-supported titanium borylimides and their reactions with TolCCH and ArFCCH (Tol = 4-C6H4Me, ArF = C6F5). Reaction of Ti{NB(NAr′CH)2}Cl2(py)3 (Ar′ = 2,6-C6H3iPr2) with Li2N2RNMe (N2RNMe = M...
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| Format: | Journal article |
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American Chemical Society
2018
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