The stereoselective birch reduction of pyrroles

The Birch reduction has been applied to electron-deficient pyrroles substituted with a chiral auxiliary at the C-2 position. Using either 8- phenylmenthol or trans-2-(α-cumyl)cyclohexanol (TCC) as auxiliaries, high levels of stereoselectivity were obtained. Moreover, the auxiliary could be removed u...

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Váldodahkkit: Donohoe, T, Guyo, P, Helliwell, M
Materiálatiipa: Journal article
Giella:English
Almmustuhtton: 1999