Synthesis of metallophosphaalkenes by reaction of organometallic nucleophiles with a phosphaethynolato-borane

We describe the reaction of a phosphaethynolato-borane [B]OCP ([B] = N,N′-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaboryl) with the organometallic nucleophile Na[Cp*Fe(CO)2] (Cp* = pentamethylcyclopentadienyl). The electrophilic character of [B]OCP allows for a new route towards the forma...

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Bibliographic Details
Main Authors: Wilson, D, Goicoechea, J
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2019