Synthesis of metallophosphaalkenes by reaction of organometallic nucleophiles with a phosphaethynolato-borane
We describe the reaction of a phosphaethynolato-borane [B]OCP ([B] = N,N′-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaboryl) with the organometallic nucleophile Na[Cp*Fe(CO)2] (Cp* = pentamethylcyclopentadienyl). The electrophilic character of [B]OCP allows for a new route towards the forma...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
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Royal Society of Chemistry
2019
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| _version_ | 1797089906795741184 |
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| author | Wilson, D Goicoechea, J |
| author_facet | Wilson, D Goicoechea, J |
| author_sort | Wilson, D |
| collection | OXFORD |
| description | We describe the reaction of a phosphaethynolato-borane [B]OCP ([B] = N,N′-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaboryl) with the organometallic nucleophile Na[Cp*Fe(CO)2] (Cp* = pentamethylcyclopentadienyl). The electrophilic character of [B]OCP allows for a new route towards the formation metal–phosphorus bonds affording a metallophosphaalkene that can be functionalised at both the oxygen and phosphorus atoms depending on the reagents employed. |
| first_indexed | 2024-03-07T03:10:46Z |
| format | Journal article |
| id | oxford-uuid:b41e2a5a-7208-421b-b7da-67b333dd2fcb |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:10:46Z |
| publishDate | 2019 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | oxford-uuid:b41e2a5a-7208-421b-b7da-67b333dd2fcb2022-03-27T04:23:55ZSynthesis of metallophosphaalkenes by reaction of organometallic nucleophiles with a phosphaethynolato-boraneJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b41e2a5a-7208-421b-b7da-67b333dd2fcbEnglishSymplectic Elements at OxfordRoyal Society of Chemistry2019Wilson, DGoicoechea, JWe describe the reaction of a phosphaethynolato-borane [B]OCP ([B] = N,N′-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaboryl) with the organometallic nucleophile Na[Cp*Fe(CO)2] (Cp* = pentamethylcyclopentadienyl). The electrophilic character of [B]OCP allows for a new route towards the formation metal–phosphorus bonds affording a metallophosphaalkene that can be functionalised at both the oxygen and phosphorus atoms depending on the reagents employed. |
| spellingShingle | Wilson, D Goicoechea, J Synthesis of metallophosphaalkenes by reaction of organometallic nucleophiles with a phosphaethynolato-borane |
| title | Synthesis of metallophosphaalkenes by reaction of organometallic nucleophiles with a phosphaethynolato-borane |
| title_full | Synthesis of metallophosphaalkenes by reaction of organometallic nucleophiles with a phosphaethynolato-borane |
| title_fullStr | Synthesis of metallophosphaalkenes by reaction of organometallic nucleophiles with a phosphaethynolato-borane |
| title_full_unstemmed | Synthesis of metallophosphaalkenes by reaction of organometallic nucleophiles with a phosphaethynolato-borane |
| title_short | Synthesis of metallophosphaalkenes by reaction of organometallic nucleophiles with a phosphaethynolato-borane |
| title_sort | synthesis of metallophosphaalkenes by reaction of organometallic nucleophiles with a phosphaethynolato borane |
| work_keys_str_mv | AT wilsond synthesisofmetallophosphaalkenesbyreactionoforganometallicnucleophileswithaphosphaethynolatoborane AT goicoecheaj synthesisofmetallophosphaalkenesbyreactionoforganometallicnucleophileswithaphosphaethynolatoborane |