Asymmetric alkylations using SuperQuat auxiliaries - an investigation into the synthesis and stability of enolates derived from 5,5-disubstituted oxazolidin-2-ones
Studies on the alkylation of enolates derived from a range of W-acyl-5,5-dimethyloxazolidin-2-ones and N-acyl-5,5diphenyloxazolidin-2-ones reveal that high yields and high diastereoselectivities are best obtained when homochiral 4-isopropyl-5,5-dimethyIoxazolidin-2-one is employed as a chiral auxili...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1999
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| _version_ | 1797089965626097664 |
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| author | Bull, S Davies, S Jones, S Sanganee, H |
| author_facet | Bull, S Davies, S Jones, S Sanganee, H |
| author_sort | Bull, S |
| collection | OXFORD |
| description | Studies on the alkylation of enolates derived from a range of W-acyl-5,5-dimethyloxazolidin-2-ones and N-acyl-5,5diphenyloxazolidin-2-ones reveal that high yields and high diastereoselectivities are best obtained when homochiral 4-isopropyl-5,5-dimethyIoxazolidin-2-one is employed as a chiral auxiliary. |
| first_indexed | 2024-03-07T03:11:39Z |
| format | Journal article |
| id | oxford-uuid:b4651913-50c1-4b61-b082-de800c3ffcd5 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:11:39Z |
| publishDate | 1999 |
| record_format | dspace |
| spelling | oxford-uuid:b4651913-50c1-4b61-b082-de800c3ffcd52022-03-27T04:25:50ZAsymmetric alkylations using SuperQuat auxiliaries - an investigation into the synthesis and stability of enolates derived from 5,5-disubstituted oxazolidin-2-onesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b4651913-50c1-4b61-b082-de800c3ffcd5EnglishSymplectic Elements at Oxford1999Bull, SDavies, SJones, SSanganee, HStudies on the alkylation of enolates derived from a range of W-acyl-5,5-dimethyloxazolidin-2-ones and N-acyl-5,5diphenyloxazolidin-2-ones reveal that high yields and high diastereoselectivities are best obtained when homochiral 4-isopropyl-5,5-dimethyIoxazolidin-2-one is employed as a chiral auxiliary. |
| spellingShingle | Bull, S Davies, S Jones, S Sanganee, H Asymmetric alkylations using SuperQuat auxiliaries - an investigation into the synthesis and stability of enolates derived from 5,5-disubstituted oxazolidin-2-ones |
| title | Asymmetric alkylations using SuperQuat auxiliaries - an investigation into the synthesis and stability of enolates derived from 5,5-disubstituted oxazolidin-2-ones |
| title_full | Asymmetric alkylations using SuperQuat auxiliaries - an investigation into the synthesis and stability of enolates derived from 5,5-disubstituted oxazolidin-2-ones |
| title_fullStr | Asymmetric alkylations using SuperQuat auxiliaries - an investigation into the synthesis and stability of enolates derived from 5,5-disubstituted oxazolidin-2-ones |
| title_full_unstemmed | Asymmetric alkylations using SuperQuat auxiliaries - an investigation into the synthesis and stability of enolates derived from 5,5-disubstituted oxazolidin-2-ones |
| title_short | Asymmetric alkylations using SuperQuat auxiliaries - an investigation into the synthesis and stability of enolates derived from 5,5-disubstituted oxazolidin-2-ones |
| title_sort | asymmetric alkylations using superquat auxiliaries an investigation into the synthesis and stability of enolates derived from 5 5 disubstituted oxazolidin 2 ones |
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