A Rhodium-Pentane sigma-alkane complex: Characterization in the solid state by experimental and computational techniques
The pentane σ–complex [Rh{Cy2P(CH2CH2)PCy2}(η2:η2–C5H12)][BArF4] is synthesized by a solid/gas single–crystal to single–crystal transformation by addition of H2 to a precursor 1,3–pentadiene complex. Characterization by low temperature single crystal X-raydiffraction (150 K) and SSNMR spectroscopy...
| Principais autores: | , , , , , |
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| Formato: | Journal article |
| Idioma: | English |
| Publicado em: |
Wiley
2016
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