Ammonium redox-responsive receptors containing two or three ferrocene redox-active centres attached to di- and tri-aza crown ether macrocycles

The binding of NH4+ to novel ferrocenyl aza crown ethers 7 and 6, respectively, containing two and three ferrocene redox-active centres attached to amine functionalised di- and tri-aza crown ether macrocycles, results in large anodic shifts of the ferrocene/ferricinium redox couple, by up to 220 mV...

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Những tác giả chính: Beer, P, Crowe, D, Main, B
Định dạng: Journal article
Ngôn ngữ:English
Được phát hành: 1989
Miêu tả
Tóm tắt:The binding of NH4+ to novel ferrocenyl aza crown ethers 7 and 6, respectively, containing two and three ferrocene redox-active centres attached to amine functionalised di- and tri-aza crown ether macrocycles, results in large anodic shifts of the ferrocene/ferricinium redox couple, by up to 220 mV with 6. © 1989.