Sweep voltammetry with a semi-circular potential waveform: electrode kinetics
We introduce a sensitive, novel way to determine the standard electrochemical rate constant, k0, through the application of a semi-circular potential wave at a microdisc electrode. A one-electron reduction reaction is investigated and simulated for varying rate constants. It is shown that the voltam...
| Main Authors: | , , |
|---|---|
| Format: | Journal article |
| Published: |
Elsevier
2019
|