BIFUNCTIONAL CHIRAL AUXILIARIES-8 - UTILIZATION OF TARTARIC ACID-DERIVED AUXILIARIES IN ALDOL AND ALKYLATION REACTIONS

BIFUNCTIONAL CHIRAL AUXILIARIES-8 - UTILIZATION OF TARTARIC ACID-DERIVED AUXILIARIES IN ALDOL AND ALKYLATION REACTIONS

The boron enolates of three new homochiral C2 symmetric 1,3-diacylimidazolidin-2-ones prepared from natural tartaric acid undergo highly diastereoselective aldol and alkylation reactions. Cleavage of these diastereomerically pure, adducts gives homochiral (1R,2S)-1-phenyl-2-methylpropane-1,3-diol an...

Deskribapen osoa

Xehetasun bibliografikoak
Egile Nagusiak:	Davies, S, Evans, G, Pearce, S
Formatua:	Journal article
Hizkuntza:	English
Argitaratua:	1994

Antzeko izenburuak

Oxazinanones as chiral auxiliaries: synthesis and evaluation in enolate alkylations and aldol reactions.
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