Development of two processes for the synthesis of bridged azabicyclic systems: intermolecular radical addition-homoallylic rearrangements leading to 2-azanorborn-5-enes and neophyl-type radical rearrangements to 2-azabenzonorbornanes.

Míreanna comhchosúla

• 2-azabenzonorbornanes from 7-azabenzonorbornanols by a nitrogen-directed neophyl-type radical rearrangement.
  de réir: Hodgson, D, et al.
  Foilsithe / Cruthaithe: (2002)
• 2-Azabicyclo[2.2.1]hept-5-enes from 7-azabicyclo[2.2.1]heptadienes by tandem intermolecular radical addition-homoallylic radical rearrangement
  de réir: Hodgson, D, et al.
  Foilsithe / Cruthaithe: (2001)
• 2-azabicyclo[2.2.1]-5-heptenes from 7-azabicyclo[2.2.1]heptadienes by tandem intermolecular radical addition - Homoallylic rearrangement.
  de réir: Hodgson, D, et al.
  Foilsithe / Cruthaithe: (2001)
• Synthesis of azabicyclic systems using nitrogen-directed radical rearrangements.
  de réir: Hodgson, D, et al.
  Foilsithe / Cruthaithe: (2007)
• Enantioselective access to isoquinuclidines by tropenone desymmetrization and homoallylic radical rearrangement: synthesis of (+)-ibogamine.
  de réir: Hodgson, D, et al.
  Foilsithe / Cruthaithe: (2005)