Uniaxial negative thermal expansion and metallophilicity in Cu3[Co(CN)6]
We report the synthesis and structural characterisation of the molecular framework copper(I)hexacyanocobaltate(III), Cu3[Co(CN)6], which we find to be isostructural to H3[Co(CN)6] and the colossalnegative thermal expansion material Ag3[Co(CN)6]. Using synchrotron X-ray powder diffraction measurements,...
| Main Authors: | , , , , , , , |
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| Format: | Journal article |
| Published: |
Elsevier
2017
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