Geometric switching of linear to area negative thermal expansion in uniaxial metal-organic frameworks
Using variable-temperature neutron powder diffraction measurements, we show that the two quartz-like metal-organic frameworks (MOFs) deuterium indium(iii) terephthalate and zinc(ii) isonicotinate exhibit anisotropic positive and negative thermal expansion (PTE/NTE) behaviour. Whereas in the former t...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2014
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