Reactivity of Cationic Terminal Borylene Complexes: Novel Mechanisms for Insertion and Metathesis Chemistry Involving Strongly Lewis Acidic Ligand Systems

The reactions of terminal borylene complexes of the type [CpFe(CO) 2(BNR2)]+ (R = i1Pr, Cy) with heteroallenes have been investigated by quantum-chemical methods, in an attempt to explain the experimentally observed product distributions. Reaction with dicyclohexylcarbodiimide (CyNCNCy) gives a bis-...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awduron: De, S, Pierce, G, Vidovic, D, Kays, D, Coombs, N, Jemmis, E, Aldridge, S
Fformat: Journal article
Iaith:English
Cyhoeddwyd: 2009