Reactivity of Cationic Terminal Borylene Complexes: Novel Mechanisms for Insertion and Metathesis Chemistry Involving Strongly Lewis Acidic Ligand Systems

The reactions of terminal borylene complexes of the type [CpFe(CO) 2(BNR2)]+ (R = i1Pr, Cy) with heteroallenes have been investigated by quantum-chemical methods, in an attempt to explain the experimentally observed product distributions. Reaction with dicyclohexylcarbodiimide (CyNCNCy) gives a bis-...

詳細記述

書誌詳細
主要な著者: De, S, Pierce, G, Vidovic, D, Kays, D, Coombs, N, Jemmis, E, Aldridge, S
フォーマット: Journal article
言語:English
出版事項: 2009