Group 4 imido complexes stabilized by a tridentate diamido-donor ligand
Reaction of the lithium amides [(2-C5H4N)C(CH3){CH2N(Li)SiMe 3}2]2 (2a) and [(2-C5H4N)C(CH3){CH2N (Li)-SiMe2tBu}2]2 (2b) with the imidotransition metal complexes [Ti(NtBu)Cl2(py)3], [Ti(N-2,6-C6H3iPr2)Cl2(py) 3], and [Zr(N-2,6-C6H3iPr2)Cl2(thf) 2] yielded the five-coordinate imido-titanium and -zirc...
| Main Authors: | , , , , , , , , |
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| Format: | Journal article |
| Jezik: | English |
| Izdano: |
2001
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