Hydrofunctionalisation of an aromatic triphosphabenzene

The aromatic heterocycle 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene reacts with a series of silanes, germanes and stannanes, with weaker E-H bonds reacting in an increasingly facile manner. All react by 1,4-addition to give bicyclic products with diastereomeric ratios varying with the substrate. D...

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Bibliographic Details
Main Authors: Falconer, R, Zeng, D, Green, M, Stephan, D, McGrady, J, Russell, C
Format: Journal article
Language:English
Published: Wiley 2019