SYNTHESIS OF 1-EPIHYDANTOCIDIN FROM D-RIBOSE

A key step in a short synthesis of 1-epihydantocidin (2) is the unanticipated transformation of azidolactones (8) and (10) to a bicyclic amine (12) induced by tetra-n-propylammonium perruthenate in the presence of morpholine-N-oxide. The structure of (12) was established by X-ray crystallographic an...

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Príomhchruthaitheoirí: Fairbanks, A, Ford, P, Watkin, D, Fleet, G
Formáid: Journal article
Foilsithe / Cruthaithe: 1993