Controlling selectivity in the rhodium-catalysed intermolecular hydroacylation reaction

Controlling selectivity in the rhodium-catalysed intermolecular hydroacylation reaction

<p>This thesis explores the area of the intermolecular hydroacylation reaction, catalysed by rhodium diphosphine complexes. A range of latent low-coordinate rhodium diphosphine complexes have been synthesised, and their catalytic activity for the hydroacylation reaction has been investigated....

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Bibliografiske detaljer
Hovedforfatter:	Pawley, R
Andre forfattere:	Weller, A
Format:	Thesis
Sprog:	English
Udgivet:	2012
Fag:	Inorganic chemistry Organometallic Chemistry

Lignende værker

Mechanistic studies of rhodium-catalysed intermolecular hydroacylation
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Tandem catalytic processes involving Rhodium-catalysed intermolecular hydroacylation
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Udgivet: (2011)

Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
af: Ylioja, P
Udgivet: (2011)

Exploring small bite-angle PNP and PCP ligands for the rhodium-catalysed intermolecular hydroacylation of b-s-substituted aldehydes with alkenes and alkynes
af: Pernik, I
Udgivet: (2014)

Exploring and exploiting selectivity in Rhodium-catalysed hydroacylation reactions
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Udgivet: (2012)

Cationic rhodium complexes with chelating phosphine and phosphine alkene ligands. Application in dehydrogenation and dehydrocoupling reactions
af: Dallanegra, R
Udgivet: (2011)

Exploring the reactivity of cationic rhodium xantphos complexes with amine-boranes
af: Johnson, H
Udgivet: (2015)

POP-type rhodium complexes in amine borane dehydropolymerisation
af: Adams, G
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Exploring the reactivity patterns of cationic and neutral rhodium bis-phosphine species with amine-boranes
af: Sewell, LJ
Udgivet: (2013)

Applications of rhodium-catalysed hydroacylation in heterocycle synthesis
af: Majhail, M
Udgivet: (2016)

Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation
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Palladium-catalysed desulfinative cross-coupling reactions: Leveraging mechanistic insights for reaction optimisation
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Borane, boryl and borylene complexes of electron rich metal centres
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Alkaline earth hydroborate complexes for the ring-opening polymerisation of cyclic esters
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Alkaline earth complexes supported by chelating diamido ligands
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Palladium-catalysed heterocycle synthesis
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Alkaline earth and rare earth complexes for the ring opening polymerisation of cyclic esters
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Solution reactivity studies of group 14 zintyl clusters towards organometallic reagents
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Group four permethylindenyl-phenoxy (PHENI*) complexes for the synthesis of polyolefins
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Dioxygen Activation by Internally Aromatic Metallacycle: Crystallographic Structure and Mechanistic Investigations
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Solution reactivity studies of group 15 Zintl anions towards unsaturated substrates
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Uranium, zirconium and hafnium eta8-permethylpentalene chemistry
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Synthesis, structure and density functional study of the ansa-rhenocene complex [Re{(η-C5H4)CMe2(η-C5H4)}Cl]
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Structure reactivity relationships in metallocene chemistry: the ansa-effect
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Solution reactivity studies of group 15 Zintl ions
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Hydrogen/deuterium exchange in alkyl-hydride derivatives of ansa-tungstenocene compounds
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Structure and dynamics of a dihydrogen/hydride ansa molybdenocene complex
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Rare earth metal boryl and gallyl compounds: synthesis and reactivity
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Bridging-terminal exchange in ansa-bridged tetrahydroborate niobocene compounds: a density functional study
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A study of the reactivity and coordination chemistry of N-heterocyclic carbenes with main group compounds
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Olefin polymerisation using group 4 permethylindenyl complexes
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Bismuth Porphyrin Antagonizes Cisplatin-Induced Nephrotoxicity via Unexpected Metallothionein-Independent Mechanisms
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Copper-catalysed β-silylation of α,β-unsaturated esters under mild reaction conditions.
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