One-pot sulfoxide synthesis exploiting a sulfinyl-dication equivalent generated from a DABSO/Trimethylsilyl Chloride sequence
A one-pot process for the synthesis of unsymmetrical sulfoxides using organometallic nucleophiles is described. Sulfur dioxide, delivered from the surrogate DABSO (DABCO-bis(sulfur dioxide)), acts as the initial electrophile and combines with the first organometallic reagent to generate a sulfinate...
| Main Authors: | , , , , |
|---|---|
| Format: | Journal article |
| Published: |
American Chemical Society
2016
|