One-pot sulfoxide synthesis exploiting a sulfinyl-dication equivalent generated from a DABSO/Trimethylsilyl Chloride sequence
A one-pot process for the synthesis of unsymmetrical sulfoxides using organometallic nucleophiles is described. Sulfur dioxide, delivered from the surrogate DABSO (DABCO-bis(sulfur dioxide)), acts as the initial electrophile and combines with the first organometallic reagent to generate a sulfinate...
Main Authors: | Willis, M, Lenstra, D, Vedovato, V, Flegeau, E, Maydom, J |
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Format: | Journal article |
Published: |
American Chemical Society
2016
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