A highly distorted open-shell endohedral Zintl cluster: [Mn@Pb12]3-.
Reaction of an ethylenediamine (en) solution of K(4)Pb(9) and 2,2,2-crypt (4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) with a tetrahydrofuran (THF) solution of Mn(3)(Mes)(6) (Mes = 2,4,6-trimethylphenyl) yielded the anionic cluster [Mn@Pb(12)](3-). This species was observed in the po...
| Main Authors: | , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2011
|