Silver-catalyzed C- to N-center remote arene migration
The 1,4-arene migration from a carbon to a nitrogen center, induced by iminyl radicals generated from radical additions to vinyl azides, is reported. Two different modes of vinyl azide activation trigger this migration process, which offers a mild route for the synthesis of trifluoromethyl- or sulfo...
Main Authors: | , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
American Chemical Society
2019
|