Silver-catalyzed C- to N-center remote arene migration

The 1,4-arene migration from a carbon to a nitrogen center, induced by iminyl radicals generated from radical additions to vinyl azides, is reported. Two different modes of vinyl azide activation trigger this migration process, which offers a mild route for the synthesis of trifluoromethyl- or sulfo...

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Hlavní autoři: Ning, Y, Mekareeya, A, Babu, K, Anderson, E, Bi, X
Médium: Journal article
Jazyk:English
Vydáno: American Chemical Society 2019