An N-heterocyclic boryloxy ligand isoelectronic with N-heterocyclic imines: access to an acyclic dioxysilylene and its heavier congeners

We introduce a new type of strongly donating N-heterocyclic boryloxy (NHBO) ligand, [(HCDippN)₂BO]¯, which is isoelectronic with the well-known N-heterocyclic iminato (NHI) donor class. This 1,3,2-diazaborole functionalized oxy ligand can be employed to stabilize the first acyclic two-coordinate dio...

Full description

Bibliographic Details
Main Authors: Aldridge, S, Loh, Y, Ying, L, Fuentes, M, Do, D
Format: Journal article
Language:English
Published: Wiley 2019