An N-heterocyclic boryloxy ligand isoelectronic with N-heterocyclic imines: access to an acyclic dioxysilylene and its heavier congeners
We introduce a new type of strongly donating N-heterocyclic boryloxy (NHBO) ligand, [(HCDippN)₂BO]¯, which is isoelectronic with the well-known N-heterocyclic iminato (NHI) donor class. This 1,3,2-diazaborole functionalized oxy ligand can be employed to stabilize the first acyclic two-coordinate dio...
| Main Authors: | , , , , |
|---|---|
| פורמט: | Journal article |
| שפה: | English |
| יצא לאור: |
Wiley
2019
|