An N-heterocyclic boryloxy ligand isoelectronic with N-heterocyclic imines: access to an acyclic dioxysilylene and its heavier congeners

An N-heterocyclic boryloxy ligand isoelectronic with N-heterocyclic imines: access to an acyclic dioxysilylene and its heavier congeners

We introduce a new type of strongly donating N-heterocyclic boryloxy (NHBO) ligand, [(HCDippN)₂BO]¯, which is isoelectronic with the well-known N-heterocyclic iminato (NHI) donor class. This 1,3,2-diazaborole functionalized oxy ligand can be employed to stabilize the first acyclic two-coordinate dio...

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Dades bibliogràfiques
Autors principals:	Aldridge, S, Loh, Y, Ying, L, Fuentes, M, Do, D
Format:	Journal article
Idioma:	English
Publicat:	Wiley 2019

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