Non-innocent behaviour of imido ligands in the reactions of silanes with half-sandwich imido complexes of Nb and V: a silane/imido coupling route to compounds with nonclassical Si--H interactions.
Reactions of imido complexes [M(Cp)(=NR')(PR''3)2] (M=V, Nb) with silanes afford a plethora of products, depending on the nature of the metal, substitution at silicon and nitrogen and the steric properties of the phosphine. The main products are [M(Cp)(=NR')(PR3)(H)(SiRnCl3-n)] (...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2008
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