A linear metal-metal bonded tri-iron single-molecule magnet
The linear trinuclear complex cation [Fe3(DpyF)4] 2+ was prepared as [Fe3(DpyF)4](BF4)22CH3CN. With large Fe–Fe distances of 2.78 Å, this complex demonstrates intramolecular ferromagnetic coupling between the anisotropic FeII centers (J/kB = +20.9(5) K) giving an ST = 6 ground state and exhibits si...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2021
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