A linear metal-metal bonded tri-iron single-molecule magnet
The linear trinuclear complex cation [Fe3(DpyF)4] 2+ was prepared as [Fe3(DpyF)4](BF4)22CH3CN. With large Fe–Fe distances of 2.78 Å, this complex demonstrates intramolecular ferromagnetic coupling between the anisotropic FeII centers (J/kB = +20.9(5) K) giving an ST = 6 ground state and exhibits si...
| Main Authors: | , , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2021
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| _version_ | 1826309222660308992 |
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| author | Srinivasan, A Musgrave, RA Rouzières, M Clérac, R McGrady, JE Hillard, EA |
| author_facet | Srinivasan, A Musgrave, RA Rouzières, M Clérac, R McGrady, JE Hillard, EA |
| author_sort | Srinivasan, A |
| collection | OXFORD |
| description | The linear trinuclear complex cation [Fe3(DpyF)4]
2+ was prepared as
[Fe3(DpyF)4](BF4)22CH3CN. With large Fe–Fe distances of 2.78 Å,
this complex demonstrates intramolecular ferromagnetic coupling
between the anisotropic FeII centers (J/kB = +20.9(5) K) giving an ST
= 6 ground state and exhibits single-molecule magnet properties. |
| first_indexed | 2024-03-07T07:30:55Z |
| format | Journal article |
| id | oxford-uuid:c04bf3ef-b12f-4990-8d27-d7e4630b22fd |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T07:30:55Z |
| publishDate | 2021 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | oxford-uuid:c04bf3ef-b12f-4990-8d27-d7e4630b22fd2023-01-16T15:49:45ZA linear metal-metal bonded tri-iron single-molecule magnetJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c04bf3ef-b12f-4990-8d27-d7e4630b22fdEnglishSymplectic ElementsRoyal Society of Chemistry2021Srinivasan, AMusgrave, RARouzières, MClérac, RMcGrady, JEHillard, EAThe linear trinuclear complex cation [Fe3(DpyF)4] 2+ was prepared as [Fe3(DpyF)4](BF4)22CH3CN. With large Fe–Fe distances of 2.78 Å, this complex demonstrates intramolecular ferromagnetic coupling between the anisotropic FeII centers (J/kB = +20.9(5) K) giving an ST = 6 ground state and exhibits single-molecule magnet properties. |
| spellingShingle | Srinivasan, A Musgrave, RA Rouzières, M Clérac, R McGrady, JE Hillard, EA A linear metal-metal bonded tri-iron single-molecule magnet |
| title | A linear metal-metal bonded tri-iron single-molecule magnet |
| title_full | A linear metal-metal bonded tri-iron single-molecule magnet |
| title_fullStr | A linear metal-metal bonded tri-iron single-molecule magnet |
| title_full_unstemmed | A linear metal-metal bonded tri-iron single-molecule magnet |
| title_short | A linear metal-metal bonded tri-iron single-molecule magnet |
| title_sort | linear metal metal bonded tri iron single molecule magnet |
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