A new reaction pathway in organophosphorus chemistry: competing S(N)2 and AE' pathways for nucleophilic attack at a phosphorus-carbon cage compound.
(Chemical Equation Presented) Competition: A combination of 31P NMR spectroscopic and calculational studies have shown that nucleophilic substitution in the phosphorus-carbon cage compound ClP3(CtBu) 2 occurs through competing SN2- and AE′-type reaction pathways (see scheme for model compound ClP3(C...
| Main Authors: | , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2006
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