Novel lead(IV) reagents for carbon-carbon bond formation
The isolation and characterisation of a range of lead(IV) complexes, prepared from achiral and chiral dicarboxylic acids, is described. These compounds have been found to be stable amorphous solids, but upon reaction with phenylboronic acid and a variety of β-dicarbonyl substrates with mercury(II) c...
| Hlavní autoři: | , , |
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| Médium: | Journal article |
| Jazyk: | English |
| Vydáno: |
1996
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| Shrnutí: | The isolation and characterisation of a range of lead(IV) complexes, prepared from achiral and chiral dicarboxylic acids, is described. These compounds have been found to be stable amorphous solids, but upon reaction with phenylboronic acid and a variety of β-dicarbonyl substrates with mercury(II) catalysis, carbon-carbon bond formation can be readily achieved. |
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