Unusual length dependence of the conductance in cumulene molecular wires

Cumulenes are sometimes described as “metallic” because an infinitely long cumulene would have the band structure of a metal. Herein, we report the single‐molecule conductance of a series of cumulenes and cumulene analogues, where the number of consecutive C=C bonds in the core is n=1, 2, 3, and 5....

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Hlavní autoři: Xu, W, Leary, E, Hou, S, Sangtarash, S, González, M, Rubio-Bollinger, G, Wu, Q, Sadeghi, H, Tejerina, L, Christensen, K, Agraït, N, Higgins, S, Lambert, C, Nichols, R, Anderson, H
Médium: Journal article
Jazyk:English
Vydáno: Wiley 2019