ASYMMETRIC-SYNTHESIS OF 2-ARYL-TETRAHYDROPYRANS VIA ARENE CHROMIUM TRICARBONYL METHODOLOGY .1. CIS-2-ARYL-4-CHLORO-TETRAHYDROPYRANS
Treatment of acetals derived from ortho substituted benzaldehyde chromium tricarbonyl complexes and methanol with homoallylic alcohol and titanium tetrachloride produces the corresponding (RS,RS,SR,RS)-cis-2-aryl-4-chloro-tetrahydropyran complexes completely diastereoselectively. Thus, by this metho...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1991
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