High-resolution EPR spectroscopic investigations of a homologous set of d9-cobalt(0), d9-rhodium(0), and d9-iridium(0) complexes.
The 17-electron complexes [M(tropp(ph))2] (M=Co0, Rh0, Ir0) were prepared and isolated (tropp = tropylidene phosphane). A structural analysis of [Co(tropp(ph))2] revealed this complex to be almost tetrahedral, while the heavier homologues have more planar structures. Partially deuterated tropp compl...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2002
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