Synthesis of cyclic alkenyl dimethylsiloxanes from alkynyl benzyldimethylsilanes and application in polyene synthesis
Cyclic dimethylalkenylsiloxanes, useful motifs for (Z)-selective Hiyama cross-coupling, are accessed from alkynyl benzyldimethylsilanes featuring adjacent allylic or homoallylic oxygen substituents by semihydrogenation/debenzylation/cyclization. While formation of 5- and 6-membered rings can be achi...
Hauptverfasser: | Gudmundsson, HG, Kuper, CJ, Cornut, D, Urbitsch, F, Elbert, BL, Anderson, EA |
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Format: | Journal article |
Sprache: | English |
Veröffentlicht: |
American Chemical Society
2019
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