Synthesis of cyclic alkenyl dimethylsiloxanes from alkynyl benzyldimethylsilanes and application in polyene synthesis

Synthesis of cyclic alkenyl dimethylsiloxanes from alkynyl benzyldimethylsilanes and application in polyene synthesis

Cyclic dimethylalkenylsiloxanes, useful motifs for (Z)-selective Hiyama cross-coupling, are accessed from alkynyl benzyldimethylsilanes featuring adjacent allylic or homoallylic oxygen substituents by semihydrogenation/debenzylation/cyclization. While formation of 5- and 6-membered rings can be achi...

書誌詳細
主要な著者:	Gudmundsson, HG, Kuper, CJ, Cornut, D, Urbitsch, F, Elbert, BL, Anderson, EA
フォーマット:	Journal article
言語:	English
出版事項:	American Chemical Society 2019

類似資料

Synthesis of cyclic alkenylsiloxanes by semihydrogenation: A stereospecific route to (Z)-alkenyl polyenes
著者:: Elbert, B, 等
出版事項: (2014)

Synthesis of cyclic alkenylsiloxanes by semihydrogenation: a stereospecific route to (Z)-alkenyl polyenes.
著者:: Elbert, B, 等
出版事項: (2014)

Copper-mediated oxidative molecular transformations of N-alkenyl/alkynyl enamine carboxylates for synthesis of azaheterocycles
著者:: Toh, Kah Kah
出版事項: (2014)

A modular, enantioselective synthesis of resolvins D3, E1, and hybrids
著者:: Urbitsch, F, 等
出版事項: (2020)

Synthesis and Characterisation of Linear and Towards Cyclic Diferrocenes with Alkynyl Spacers
著者:: Lucy E. Wilson, 等
出版事項: (2018-09-01)

Molecular Iodine-Mediated Cyclization of Tethered Heteroatom-Containing Alkenyl or Alkynyl Systems
著者:: Malose Jack Mphahlele
出版事項: (2009-11-01)

Inorganic-base-mediated hydroamination of alkenyl oximes for the synthesis of cyclic nitrones
著者:: Peng, Xingao, 等
出版事項: (2014)

Recent Developments in Transition-Metal Catalyzed Direct C–H Alkenylation, Alkylation, and Alkynylation of Azoles
著者:: Su Chen, 等
出版事項: (2020-10-01)

WELL-DEFINED SYNTHESIS OF POLY(DIMETHYLSILOXANE) HOMOPOLYMERS
著者:: M.D. Ninago, 等
出版事項: (2009-05-01)

Palladium-catalyzed asymmetric synthesis of 2-alkynyl oxacycles.
著者:: Daniels, D, 等
出版事項: (2011)

Initial Examinations of the Diastereoselectivity and Chemoselectivity of Intramolecular Silyl Nitronate [3+2] Cycloadditions with Alkenyl/Alkynyl Nitroethers
著者:: Katelyn Stevens, 等
出版事項: (2024-12-01)

Synthesis and properties of 6-alkynyl-5-aryluracils
著者:: Ruben Manuel Figueira de Abreu, 等
出版事項: (2024-04-01)

The synthesis and applications of cyclic alkenylsiloxanes
著者:: Elbert, B, 等
出版事項: (2014)

Regioselective alkynylation followed by Suzuki coupling of 2,4-dichloroquinoline: Synthesis of 2-alkynyl-4-arylquinolines
著者:: Ellanki A. Reddy, 等
出版事項: (2009-07-01)

Ni-Catalyzed Cross-Electrophile Coupling for the Synthesis of Skipped Polyenes
著者:: McGeough, Catherine P., 等
出版事項: (2020)

Synthesis and optical properties of bis- and tris-alkynyl-2-trifluoromethylquinolines
著者:: Stefan Jopp, 等
出版事項: (2024-05-01)

Preparation and Utility of <i>N</i>-Alkynyl Azoles in Synthesis
著者:: Brandon Reinus, 等
出版事項: (2019-01-01)

MESO-ALKYNYL PORPHYRINS
著者:: Anderson, H
出版事項: (1992)

Synthesis and reactions of alkenyl-gem-dichlorocyclopropanes obtained from piperylene
著者:: A. I. Musin, 等
出版事項: (2020-11-01)

Cyclic alkenylsiloxanes: synthesis and application towards incednam
著者:: Gudmundsson, H
出版事項: (2016)

Synthesis and biology of resolvins D3, E1 and hybrids and synthesis of bridge-substituted bicyclo[1.1.1]pentanes
著者:: Urbitsch, F
出版事項: (2019)

Development of an enolate alkynylation approach towards the synthesis of the taiwanschirin natural products
著者:: Haughey, M, 等
出版事項: (2021)

Rate Dependence on Inductive and Resonance Effects for the Organocatalyzed Enantioselective Conjugate Addition of Alkenyl and Alkynyl Boronic Acids to β-Indolyl Enones and β-Pyrrolyl Enones
著者:: Amy Boylan, 等
出版事項: (2021-03-01)

Direct synthesis of Z-alkenyl halides through catalytic cross-metathesis
著者:: Koh, Ming Joo, 等
出版事項: (2017)

Modular Synthesis of Highly Substituted Pyridines via Enolate α-Alkenylation.
著者:: Hardegger, L, 等
出版事項: (2015)

Cobalt-catalyzed hydrothiolation of alkynes for the diverse synthesis of branched alkenyl sulfides
著者:: Jiale Ying, 等
出版事項: (2024-09-01)

Synthesis of alkynyl-substituted camphor derivatives and their use in the preparation of paclitaxel-related compounds
著者:: M. Fernanda N. N. Carvalho, 等
出版事項: (2017-06-01)

Hydroamination of alkenyl N-arylhydrazones mediated by t-BuOK for the synthesis of nitrogen heterocycles
著者:: Peng, Xingao, 等
出版事項: (2022)

Synthesis of the C50 diastereomers of the C33-C51 fragment of stambomycin D
著者:: Wang, Y, 等
出版事項: (2021)

Formation of New Alkynyl(phenyl)iodonium Salts and Their Use in the Synthesis of Phenylsulfonyl Indenes and Acetylenes
著者:: A. Varvoglis, 等
出版事項: (2005-10-01)

Ionic Liquids Enhanced Alkynyl Schiff Bases Derivatives of Fipronil Synthesis and Their Cytotoxicity Studies
著者:: Xiu Liu, 等
出版事項: (2019-09-01)

Energetics and Dynamics of the Low-Lying Electronic States of Constrained Polyenes: Implications for Infinite Polyenes
著者:: Christensen, Ronald L., 等
出版事項: (2015)

Copper-mediated synthesis of N-alkenyl-α,β-unsaturated nitrones and their conversion to tri- and tetrasubstituted pyridines
著者:: Dimitra Kontokosta, 等
出版事項: (2015-11-01)

Ligand bite angle-dependent palladium-catalyzed cyclization of propargylic carbonates to 2-alkynyl azacycles or cyclic dienamides.
著者:: Daniels, D, 等
出版事項: (2014)

Tandem copper-catalysed aryl and alkenyl amination reactions: the synthesis of N-functionalised indoles.
著者:: Hodgkinson, R, 等
出版事項: (2009)

One-Pot Sequential Synthesis of Alkenylated Dihydroquinolinones and Hexahydroacridinones in Deep Eutectic Solvent Medium
著者:: Sundararajan Suresh, 等
出版事項: (2024-08-01)

Enantioselective synthesis of α-aminoboronates by NiH-catalysed asymmetric hydroamidation of alkenyl boronates
著者:: Yao Zhang, 等
出版事項: (2022-09-01)

Highly selective synthesis of all-carbon tetrasubstituted alkenes by deoxygenative alkenylation of carboxylic acids
著者:: Yantao Li, 等
出版事項: (2022-02-01)

Synthesis of 3-Alkenyl-1-azaanthraquinones via Diels-Alder and Electron Transfer Reactions
著者:: Patrice Vanelle, 等
出版事項: (2002-12-01)

Experimental Modelling of Autoignition Temperature for Alkyl/Alkenyl Products from Fischer-Tropsch Synthesis
著者:: Skřínský Jan, 等
出版事項: (2018-01-01)