Synthesis of cyclic alkenyl dimethylsiloxanes from alkynyl benzyldimethylsilanes and application in polyene synthesis

Synthesis of cyclic alkenyl dimethylsiloxanes from alkynyl benzyldimethylsilanes and application in polyene synthesis

Cyclic dimethylalkenylsiloxanes, useful motifs for (Z)-selective Hiyama cross-coupling, are accessed from alkynyl benzyldimethylsilanes featuring adjacent allylic or homoallylic oxygen substituents by semihydrogenation/debenzylation/cyclization. While formation of 5- and 6-membered rings can be achi...

Полное описание

Библиографические подробности
Главные авторы:	Gudmundsson, HG, Kuper, CJ, Cornut, D, Urbitsch, F, Elbert, BL, Anderson, EA
Формат:	Journal article
Язык:	English
Опубликовано:	American Chemical Society 2019

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