Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.

It's all in the ligand: By choice of the appropriate diphosphine ligand a previously linear-selective alkyne hydroacylation process can be "switched" to be highly branched-selective (see scheme, l=linear, b=branched). Structural data for the ortho-iPr-dppe-rhodium catalyst suggest res...

সম্পূর্ণ বিবরণ

গ্রন্থ-পঞ্জীর বিবরন
প্রধান লেখক: González-Rodríguez, C, Pawley, R, Chaplin, AB, Thompson, A, Weller, A, Willis, M
বিন্যাস: Journal article
ভাষা:English
প্রকাশিত: 2011