Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.
It's all in the ligand: By choice of the appropriate diphosphine ligand a previously linear-selective alkyne hydroacylation process can be "switched" to be highly branched-selective (see scheme, l=linear, b=branched). Structural data for the ortho-iPr-dppe-rhodium catalyst suggest res...
Full description
Bibliographic Details
| Main Authors: |
González-Rodríguez, C,
Pawley, R,
Chaplin, AB,
Thompson, A,
Weller, A,
Willis, M |
|---|
| Format: | Journal article
|
|---|
| Language: | English |
|---|
| Published: |
2011
|
|---|