Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.
It's all in the ligand: By choice of the appropriate diphosphine ligand a previously linear-selective alkyne hydroacylation process can be "switched" to be highly branched-selective (see scheme, l=linear, b=branched). Structural data for the ortho-iPr-dppe-rhodium catalyst suggest res...
সম্পূর্ণ বিবরণ
গ্রন্থ-পঞ্জীর বিবরন
| প্রধান লেখক: |
González-Rodríguez, C,
Pawley, R,
Chaplin, AB,
Thompson, A,
Weller, A,
Willis, M |
|---|
| বিন্যাস: | Journal article
|
|---|
| ভাষা: | English |
|---|
| প্রকাশিত: |
2011
|
|---|