Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.
It's all in the ligand: By choice of the appropriate diphosphine ligand a previously linear-selective alkyne hydroacylation process can be "switched" to be highly branched-selective (see scheme, l=linear, b=branched). Structural data for the ortho-iPr-dppe-rhodium catalyst suggest res...
| Những tác giả chính: | , , , , , |
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| Định dạng: | Journal article |
| Ngôn ngữ: | English |
| Được phát hành: |
2011
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| _version_ | 1826295396040704000 |
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| author | González-Rodríguez, C Pawley, R Chaplin, AB Thompson, A Weller, A Willis, M |
| author_facet | González-Rodríguez, C Pawley, R Chaplin, AB Thompson, A Weller, A Willis, M |
| author_sort | González-Rodríguez, C |
| collection | OXFORD |
| description | It's all in the ligand: By choice of the appropriate diphosphine ligand a previously linear-selective alkyne hydroacylation process can be "switched" to be highly branched-selective (see scheme, l=linear, b=branched). Structural data for the ortho-iPr-dppe-rhodium catalyst suggest restricted rotation of the phosphine aryl units may be responsible for the observed selectivity. Copyright © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| first_indexed | 2024-03-07T04:00:22Z |
| format | Journal article |
| id | oxford-uuid:c45ef674-864b-4eea-b64d-a80ec33c49c0 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:00:22Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:c45ef674-864b-4eea-b64d-a80ec33c49c02022-03-27T06:22:53ZRhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c45ef674-864b-4eea-b64d-a80ec33c49c0EnglishSymplectic Elements at Oxford2011González-Rodríguez, CPawley, RChaplin, ABThompson, AWeller, AWillis, MIt's all in the ligand: By choice of the appropriate diphosphine ligand a previously linear-selective alkyne hydroacylation process can be "switched" to be highly branched-selective (see scheme, l=linear, b=branched). Structural data for the ortho-iPr-dppe-rhodium catalyst suggest restricted rotation of the phosphine aryl units may be responsible for the observed selectivity. Copyright © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| spellingShingle | González-Rodríguez, C Pawley, R Chaplin, AB Thompson, A Weller, A Willis, M Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch. |
| title | Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch. |
| title_full | Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch. |
| title_fullStr | Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch. |
| title_full_unstemmed | Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch. |
| title_short | Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch. |
| title_sort | rhodium catalyzed branched selective alkyne hydroacylation a ligand controlled regioselectivity switch |
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