Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.

It's all in the ligand: By choice of the appropriate diphosphine ligand a previously linear-selective alkyne hydroacylation process can be "switched" to be highly branched-selective (see scheme, l=linear, b=branched). Structural data for the ortho-iPr-dppe-rhodium catalyst suggest res...

书目详细资料
Main Authors:	González-Rodríguez, C, Pawley, R, Chaplin, AB, Thompson, A, Weller, A, Willis, M
格式:	Journal article
语言:	English
出版:	2011

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