Dehydrogenation of saturated CC and BN bonds at cationic N-heterocyclic carbene stabilized M(III) centers (M = Rh, Ir).
Chloride abstraction from the group 9 metal bis(N-heterocyclic carbene) complexes M(NHC)(2)(H)(2)Cl [M = Rh, Ir; NHC = IPr = N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene or IMes = N,N'-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] leads to the formation of highly reactive cationic spe...
| Auteurs principaux: | , , |
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| Format: | Journal article |
| Langue: | English |
| Publié: |
2010
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