Experimental validation of Marcus theory for outer-sphere heterogeneous electron-transfer reactions: the oxidation of substituted 1,4-phenylenediamines.
Rate constants depend on molecular size: Results are presented to validate the relationship between molecular size and the standard electrochemical rate constant predicted by Marcus theory (see graphic). Measurement of hydrodynamic radii and electron-transfer rates for substituted 1,4-phenylenediami...
| Päätekijät: | , , , , |
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| Aineistotyyppi: | Journal article |
| Kieli: | English |
| Julkaistu: |
2004
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