Electrochemical origin of hysteresis in the electron-transfer reactions of adsorbed proteins: Contrasting behavior of the "blue" copper protein, azurin, adsorbed on pyrolytic graphite and modified gold electrodes
Azurin and other small redox proteins exhibit fast electron transfer when adsorbed on a pyrolytic graphite "edge" electrode, but close examination reveals unusual electrochemical behavior that is not predicted by simple models. Cyclic voltammetry over a wide range of scan rates (up to 1000...
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Format: | Journal article |
Language: | English |
Published: |
2001
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