Molecular dynamics in solid bis(eta-arene)molybdenum complexes studied by solid-state deuterium nuclear magnetic resonance spectroscopy

Variable-temperature solid-state 2H NMR spectra have been recorded on microcrystalline samples of [Mo(η-C6D6)2], [Mo{η-C6D3(CD3)3-1,3,5} 2] and [ZrS2{Mo[η-C6D3(CD3) 3-1,3,5]2}0.15]. In the case of [Mo(η-C6D6)2] the spectra are invariant in the range 160-360 K and are consistent with rapid ring rotat...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид: OHare, D, Heyes, S, Barlow, S, Mason, S
Формат: Journal article
Хэвлэсэн: 1996