Synthesis, DFT studies, and reactions of scandium and yttrium dialkyl cations containing neutral fac-N-3 and fac-S-3 donor ligands
Reaction of Sc(CH2SiMe3)3(THF)2 with 1,4,7-trithiacyclononane gave Sc([9]aneS3)(CH 2SiMe3)3, the first organometallic group 3 complex of [9]aneS3 ([9]aneS3 = 1,4,7-trithiacyclononane). The corresponding reaction for yttrium gave equilibrium mixtures of Y([9]aneS3)(CH2SiMe3)3 and starting materials....
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2008
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