RADICAL REACTIONS IN SYNTHESIS - INTRAMOLECULAR SH2' MACROCYCLISATIONS
The synthesis of 10-15 membered α-methylene lactones 1 from the functionalised allyl stannanes 2 occurs cleanly in moderate to high yield under free radical conditions via an intramolecular SH2′ reaction.
Main Authors: | Baldwin, J, Adlington, R, Mitchell, M, Robertson, J |
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Format: | Journal article |
Language: | English |
Published: |
1990
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