Cationic rhodium complexes with chelating phosphine and phosphine alkene ligands. Application in dehydrogenation and dehydrocoupling reactions

Cationic rhodium complexes with chelating phosphine and phosphine alkene ligands. Application in dehydrogenation and dehydrocoupling reactions

<p>A series of cationic Rh(I) diphosphine and phosphine-alkene complexes have been isolated and fully characterised. The reactivity of these species towards hydrogenation, dehydrogenation and dehydrocoupling reactions has been investigated.</p><p>The use of potentially hemilabile l...

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Bibliografiske detaljer
Hovedforfatter:	Dallanegra, R
Andre forfattere:	Weller, A
Format:	Thesis
Sprog:	English
Udgivet:	2011
Fag:	Catalysis Organometallic Chemistry Inorganic chemistry

Lignende værker

Exploring the reactivity patterns of cationic and neutral rhodium bis-phosphine species with amine-boranes
af: Sewell, LJ
Udgivet: (2013)

Exploring small bite-angle PNP and PCP ligands for the rhodium-catalysed intermolecular hydroacylation of b-s-substituted aldehydes with alkenes and alkynes
af: Pernik, I
Udgivet: (2014)

Exploring the reactivity of cationic rhodium xantphos complexes with amine-boranes
af: Johnson, H
Udgivet: (2015)

Controlling selectivity in the rhodium-catalysed intermolecular hydroacylation reaction
af: Pawley, R
Udgivet: (2012)

Alkaline earth complexes supported by chelating diamido ligands
af: Haynes, M
Udgivet: (2024)

Revealing the P-B coupling event in the rhodium catalysed dehydrocoupling of phosphine-boranes H3B center dot PR2H (R = Bu-t, Ph)
af: Huertos, M, et al.
Udgivet: (2013)

POP-type rhodium complexes in amine borane dehydropolymerisation
af: Adams, G
Udgivet: (2018)

Reaction and separation system for CO2 hydrogenation to formic acid catalyzed by iridium immobilized on solid phosphines under base-free condition
af: Jinling Hu, et al.
Udgivet: (2023-05-01)

Alkaline earth and rare earth complexes for the ring opening polymerisation of cyclic esters
af: Clark, L
Udgivet: (2012)

Mechanistic studies of rhodium-catalysed intermolecular hydroacylation
af: Barwick-Silk, J
Udgivet: (2018)

Zintl ions as molecular analogues of liquid alloys for C–H activation
af: Townrow, OPE
Udgivet: (2022)

Dioxygen Activation by Internally Aromatic Metallacycle: Crystallographic Structure and Mechanistic Investigations
af: Zhihong Deng, et al.
Udgivet: (2020-08-01)

Alkyl dehydrogenation in iridium tri-cyclopentyl phosphines
af: Moret, S, et al.
Udgivet: (2010)

Structure, reactivity, and solid-gas catalysis in ligand-varied solid-state molecular organometallic systems
af: Royle, C
Udgivet: (2021)

Structure reactivity relationships in metallocene chemistry: the ansa-effect
af: Conway, S
Udgivet: (2000)

Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
af: Ylioja, P
Udgivet: (2011)

I. Discovery and development of nickel-catalyzed 1,2-dicarbofunctionalization reactions of alkenes II. Synthesis and reactivity of nucleophilic calcium fluoride complexes with oxygenic ligand frameworks
af: Apolinar, O
Udgivet: (2024)

Intramolecular alkyl phosphine dehydrogenation in cationic rhodium complexes of tris(cyclopentylphosphine).
af: Douglas, T, et al.
Udgivet: (2008)

GROUP III permethylindenyl-phenoxy complexes for biorenewable polymer synthesis
af: Hayden, JA
Udgivet: (2024)

New main group and rare earth complexes and their applications in the ring-opening polymerisation of cyclic esters
af: Cushion, M, et al.
Udgivet: (2011)

Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions
af: Luo, Ding
Udgivet: (2010)

Investigating the chemistry of cationic rhodium bisphosphine complexes: comparing reactivity in the solid state with solution
af: Pike, SD
Udgivet: (2014)

Study on the Effect of the Ligand Structure in Palladium Organometallic Catalysts in the Suzuki–Miyaura Cross-Coupling Reaction
af: Paula Munín-Cruz, et al.
Udgivet: (2021-11-01)

Syntheses and anti-cancer evaluation of optically pure gold (I) phosphine complexes
af: Li, Binbin
Udgivet: (2016)

Ligand modification and catalysis : water-soluble phosphines and chiral cyclopentadienes.
af: Feitler, David
Udgivet: (2005)

Catalytic asymmetric carbon-carbon bond formation using alkenes as alkylmetal equivalents
af: Maksymowicz, R
Udgivet: (2014)

Borane, boryl and borylene complexes of electron rich metal centres
af: Addy, D, et al.
Udgivet: (2012)

Alkaline earth hydroborate complexes for the ring-opening polymerisation of cyclic esters
af: Diteepeng, N
Udgivet: (2018)

Preparation of chiral EC(sp3)E’ phosphine-based mono- and di-nuclear palladium pincer complexes
af: Tay, Wee Shan
Udgivet: (2016)

Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines
af: Huang, Yinhua
Udgivet: (2012)

Rhodium "PONOP" pincer complexes for amine-borane dehydrogenation
af: Spearing-Ewyn, EAK
Udgivet: (2020)

The synthesis and study of titanium amidinate complexes as olefin polymerisation catalysts
af: Scharbert, MT
Udgivet: (2018)

Asymmetric synthesis of chiral arsines and phosphines and their stability investigation
af: Ma, Meng Tao
Udgivet: (2009)

Indenyl and diazene chemistry
af: Ransom, P
Udgivet: (2009)

Synthesis, Characterization And Structural Studies Of Palladium(Ii) Complexes With Some Substituted Phosphine And Arsine Ligands
af: Mohidin Yahya, Hamdya Farhana
Udgivet: (2018)

The synthesis and reactivity of Group 4 metal hydrazides
af: Schofield, ADH
Udgivet: (2012)

Synthesis of novel phosphine ligands
af: Dai, Xuedong, 1970-
Udgivet: (2007)

Group four permethylindenyl-phenoxy (PHENI*) complexes for the synthesis of polyolefins
af: Collins Rice, CG
Udgivet: (2023)

Base Metal Complexes as Homogeneous Catalysts and Enzyme Mimics
af: Xile Hu
Udgivet: (2011-09-01)

Synthesis and reactivity of alkaline earth and aluminium gallyl complexes
af: Reyes Sánchez, JA
Udgivet: (2018)